To unlock this achievement you simply need to create ammunition at your Home Base five times. You can access your Home Base's facilities by pushing up on your D-Pad. RB over to the Home tab to view your available facilities. You must have a library (to research the knowledge) and a workshop (which needs upgrading into a munition shop) facility built in order to create ammunition. Build these facilities if you need them, select the munition shop, and choose any weapon caliber you want. It takes 4 minutes to create ammo. Initiate the task 5 times and in 20 minutes the achievement will be yours.